Compressing $\Theta$-chain in slit geometry

Abstract

When compressed in a slit of width $D$, a $\Theta$-chain that displays the scaling of size $R_0$ (diameter) with respect to the number of monomers $N$, $R_0\sim a{N}^{1/2}$, expands in the lateral direction as $R_{\parallel }\sim a{N}^{\nu }(a/D{)}^{2\nu -1}$. Provided that the $\Theta$ condition is strictly maintained throughout the compression, the well-known scaling exponent of $\Theta$-chain in 2 dimensions, $\nu =4/7$, is anticipated in a perfect confinement. However, numerics shows that upon increasing compression from $R_0/D<1$ to $R_0/D\gg 1$, $\nu$ gradually deviates from $\nu =1/2$ and plateaus at $\nu =3/4$, the exponent associated with the self-avoiding walk in two dimensions. Using both theoretical considerations and numerics, we argue that it is highly nontrivial to maintain the $\Theta$ condition under confinement because of two major effects. First, as the dimension is reduced from 3 to 2 dimensions, the contributions of higher order virial terms, which can be ignored in 3 dimensions at large $N$, become significant. Second and more importantly, the geometrical confinement, which is regarded as an applied external field, alters the second virial coefficient ($B_2$) changes from $B_2=0$ ($\Theta$ condition) in free space to $B_2>0$ (good-solvent condition) in confinement. Our study provides practical insight into how confinement affects the conformation of a single polymer chain.

arXiv comment31 pages, 4 figures

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Cited by in corpus (1)

• Irregularity of polymer domain boundaries in two-dimensional polymer solution