Local Density Fluctuation Governs the Divergence of Viscosity underlying Elastic and Hydrodynamic Anomalies in a 2D Glass-Forming Liquid

Abstract

If a liquid is cooled rapidly to form a glass, its structural relaxation becomes retarded, producing a drastic increase in viscosity. In two dimensions, strong long-wavelength fluctuations persist, even at low temperature, making it difficult to evaluate the microscopic structural relaxation time. This Letter shows that, in a 2D glass-forming liquid, relative displacement between neighbor particles yields a relaxation time that grows in proportion to the viscosity. In addition to thermal elastic vibrations, hydrodynamic fluctuations are found to affect the long-wavelength dynamics, yielding a logarithmically diverging diffusivity in the long-time limit.

6 pages, 4 figures + Supplemental Material (4 pages, 3 figures); introduction is largely revised. Data of stress correlation functions are added