The effect of non-superconducting dopants (Mn, V, Cr and Cu) on the nematic fluctuations in iron-based superconductors

Abstract

We have systematically studied the nematic susceptibility in non-superconducting Ba(Fe${}_{1-x}$TM${}_x$)${}_2$As${}_2$ (TM = Cr, Mn, V and Cu) by measuring the uniaxial pressure dependence of the resistivity along the Fe-As-Fe direction. The nematic susceptibilities in all samples show the Curie-Weiss-like behavior at high temperatures, where the nematic Curie constant $A_n$ can be derived, similar to the Curie constant in a paramagnetism. While all these dopants do not introduce superconductivity in BaFe${}_2$As${}_2$, their effects on nematic fluctuations are different. In Mn, Cr and V doped samples, $|A_n|$ decreases significantly with the increasing doping level. On the other hand, $|A_n|$ increases dramatically with Cu doping, similar to the superconducting Ni-doped BaFe${}_2$As${}_2$. However, the nematic susceptibility is suppressed at low temperatures for $x$ larger than $0.04$, which may be related to the short-range antiferromagnetic order that survives up to very high doping level. Doping Mn, Cr and Cu into the optimally-doped superconducting BaFe${}_2$(As${}_{0.69}$P${}_{0.31}$)${}_2$ also strongly reduces $|A_n|$. Compared with those systems that clearly exhibit superconductivity, such as Ni, K or P doped samples, our results suggest a strong connection between the nematic and spin degrees of freedom. Moreover, the reason of the suppression of superconductivity by dopants such as Cr, Mn, V and Cu may be correlated with the suppression of nematic fluctuations.

8 pages, 5 figures