Spontaneous doping of the basal plane of MoS2 single-layers through oxygen substitution under ambient conditions

Abstract

The chemical inertness of the defect-free basal plane confers environmental stability to MoS2 single-layers, but it also limits their chemical versatility and catalytic activity. The stability of the pristine MoS2 basal plane against oxidation under ambient conditions is a widely accepted assumption in the interpretation of various studies and applications. However, single-atom level structural investigations reported here reveal that oxygen atoms spontaneously incorporate into the basal plane of MoS2 single layers during ambient exposure. Our scanning tunneling microscopy investigations reveal a slow oxygen substitution reaction, upon which individual sulfur atoms are one by one replaced by oxygen, giving rise to solid solution type 2D MoS2-xOx crystals. O substitution sites present all over the basal plane act as single-atomic active reaction centers, substantially increasing the catalytic activity of the entire MoS2 basal plane for the electrochemical H2 evolution reaction.

6 pages, 5 figures

References in corpus (2)

• Strong Photoluminescence Enhancement of MoS2 through Defect Engineering and Oxygen Bonding
• Two-dimensional transition metal dichalcogenides under electron irradiation: defect production and doping

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• Defect Engineering of Two-dimensional Molybdenum Disulfide
• Twist angle dependent electronic properties of exfoliated single layer MoS${}_2$ on Au(111)
• Defects, band bending and ionization rings in MoS2
• Kondo Impurities in Two Dimensional MoS2 for Achieving Ultrahigh Thermoelectric Powerfactor
• Roadmap and direction towards high performance MoS2 hydrogen evolution catalysts