Substrate-dependent Photoconductivity Dynamics in a High-efficiency Hybrid Perovskite Alloy

Ali Moeed Tirmzi; Jeffrey A. Christians; Ryan P. Dwyer; David T. Moore; John A. Marohn

doi:10.1021/acs.jpcc.8b11783

paper

Substrate-dependent Photoconductivity Dynamics in a High-efficiency Hybrid Perovskite Alloy

arXiv:1812.02135 · doi:10.1021/acs.jpcc.8b11783

Abstract

Films of (FA $_{0.79}$ MA $_{0.16}$ Cs $_{0.05}$ ) $_{0.97}$ Pb(I $_{0.84}$ Br $_{0.16}$ ) $_{2.97}$ were grown over TiO $_{2}$ , SnO $_{2}$ , ITO, and NiO. Film conductivity was interrogated by measuring the in-phase and out-of-phase forces acting between the film and a charged microcantilever. We followed the films' conductivity vs. time, frequency, light intensity, and temperature (233 to 312 K). Perovskite conductivity was high and light-independent over ITO and NiO. Over TiO $_{2}$ and SnO $_{2}$ , the conductivity was low in the dark, increased with light intensity, and persisted for 10's of seconds after the light was removed. At elevated temperature over TiO $_{2}$ , the rate of conductivity recovery in the dark showed an activated temperature dependence (E $_{a}$ = 0.58 eV). Surprisingly, the light-induced conductivity over TiO $_{2}$ and SnO $_{2}$ relaxed essentially instantaneously at low temperature. We use a transmission-line model for mixed ionic-electronic conductors to show that the measurements presented are sensitive to the sum of electronic and ionic conductivities. We rationalize the seemingly incongruous observations using the idea that holes, introduced either by equilibration with the substrate or via optical irradiation, create iodide vacancies.

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Light-dependent Impedance Spectra and Transient Photoconductivity in a Ruddlesden-Popper 2D Lead-halide Perovskite Revealed by Electrical Scanned Probe Microscopy and Accompanying Theory