Martingale theory for housekeeping heat

Abstract

The housekeeping heat is the energy exchanged between a system and its environment in a nonequilibrium process that results from the violation of detailed balance. We describe fluctuations of the housekeeping heat in mesoscopic systems using the theory of martingales, a mathematical framework widely used in probability theory and finance. We show that the exponentiated housekeeping heat (in units of $k_{\mathrm{B}}T$, with $k_{\mathrm{B}}$ the Boltzmann constant and $T$ the temperature) of a Markovian nonequilibrium process under arbitrary time-dependent driving is a martingale process. From this result, we derive universal equalities and inequalities for the statistics of stopping-times and suprema of the housekeeping heat. We test our results with numerical simulations of a system driven out of equilibrium and described by Langevin dynamics.

7 pages, 2 figures