paper

Monatomic Co, CoO $_{2}$ , and CoO $_{3}$ Nanowires on Ir(100) and Pt(100) surfaces: Formation, Structure, and Energetics

arXiv:1810.08574 · doi:10.1103/PhysRevB.96.085407

Abstract

In this study we investigate the structural and chemical changes of monatomic CoO $_{2}$ chains grown self-organized on the Ir(100) surface [P. Ferstl et al., PRL 117, 2016, 046101] and on Pt(100) under reducing and oxidizing conditions. By a combination of quantitative low-energy electron diffraction, scanning tunnelling microscopy, and density functional theory we show that the cobalt oxide wires are completely reduced by H $_{2}$ at temperatures above 320 K and a 3x1 ordered Ir $_{2}$ Co or Pt $_{2}$ Co surface alloy is formed. Depending on temperature the surface alloy on Ir(100) is either hydrogen covered (T < 400 K) or clean and eventually undergoes an irreversible order-disorder transition at about 570 K. The Pt $_{2}$ Co surface alloy disorders with the desorption of hydrogen, whereby Co submerges into subsurface sites. Vice versa, applying stronger oxidants than O $_{2}$ such as NO $_{2}$ leads to the formation of CoO3 chains on Ir(100) in a 3x1 superstructure. On Pt(100) such a CoO $_{3}$ phase could not be prepared so far, which however, is due to the UHV conditions of our experiments. As revealed by theory this phase will become stable in a regime of higher pressure. In general, the structures can be reversibly switched on both surfaces using the respective agents O $_{2}$ , NO $_{2}$ and H $_{2}$ .

13 pages, 10 figures

Monatomic Co, CoO2​, and CoO3​ Nanowires on Ir(100) and Pt(100) surfaces: Formation, Structure, and Energetics

Abstract

Monatomic Co, CoO $_{2}$ , and CoO $_{3}$ Nanowires on Ir(100) and Pt(100) surfaces: Formation, Structure, and Energetics