Linear complex susceptibility of long range interacting dipoles acted on by thermal agitation and weak external ac fields
arXiv:1810.08150 · doi:10.1103/PhysRevB.99.024304
Abstract
An analytical formula for the linear complex susceptibility of dipolar assemblies subjected to thermal agitation, long range interactions and an externally applied uniform sinusoidal field of weak amplitude is derived using the forced rotational diffusion equation of Cugliandolo et al. [Phys. Rev. E 91, 032139 (2015)] in the virial approximation. If the Kirkwood correlation factor of the dipolar assembly gK exceeds unity, a thermally activated process arising from the interaction-specific component arises while for gK<1, the susceptibility spectrum normalized by its static value is practically unaltered with respect to that of the ideal gas phase.
References in corpus (4)
- Langevin Equation for the Density of a System of Interacting Langevin Processes
- Disentangling density and temperature effects in the viscous slowing down of glassforming liquids
- Magnetic relaxation of a system of superparamagnetic particles weakly coupled by dipole-dipole interactions
- Stochastic dynamics of collective modes for Brownian dipoles
Cited by in corpus (9)
- Universal Structural Relaxation in Supercooled Liquids
- Dipole-dipole correlations and the Debye process in the dielectric response of non-associating glass forming liquids
- Intermolecular Cross-Correlations in the Dielectric Response of Glycerol
- Molecular mechanism of the Debye relaxation in monohydroxy alcohols revealed from rheo-dielectric spectroscopy
- The computational evidence for the crucial role of the dipole cross-correlations in the polar glass-forming liquids
- On the Spectral Shape of the Structural Relaxation in Deeply Supercooled Liquids
- Third and Fifth Harmonic Responses in Viscous Liquids
- Computing dielectric spectra in molecular dynamics simulations: using a cavity to disentangle self and cross correlations
- A Fresh Perspective on Water Dynamics in Aqueous Salt Solutions