The Equation of State of MH-III: a possible deep CH${}_4$ reservoir in Titan, Super-Titan exoplanets and moons

Abstract

We investigate the thermal equation of state, bulk modulus, thermal expansion coefficient, and heat capacity of MH-III (CH${}_4$ filled-ice Ih), needed for the study of CH${}_4$ transport and outgassing for the case of Titan and super-Titans. We employ density functional theory and ab initio molecular dynamics simulations in the generalized-gradient approximation with a van der Waals functional. We examine the finite temperature range of $300$K-$500$K and pressures between $2$GPa-$7$GPa. We find that in this P-T range MH-III is less dense than liquid water. There is uncertainty in the normalized moment of inertia (MOI) of Titan; it is estimated to be in the range of $0.33-0.34$. If Titan's MOI is $0.34$, MH-III is not stable at present in Titan's interior, yielding an easier path for the outgassing of CH${}_4$. However, for an MOI of $0.33$, MH-III is thermodynamically stable at the bottom of a ice-rock internal layer capable of storing CH${}_4$. For rock mass fractions $⪅0.2$ upwelling melt is likely hot enough to dissociate MH-III along its path. For super-Titans considering a mixture of MH-III and ice VII, melt is always positively buoyant if the H${}_2$O:CH${}_4$ mole fraction is $>5.5$. Our thermal evolution model shows that MH-III may be present today in Titan's core, confined to a thin ($\approx 10$km) outer shell. We find that the heat capacity of MH-III is higher than measured values for pure water-ice, larger than heat capacity often adopted for ice-rock mixtures with implications for internal heating.

23 pages, 23 figures, accepted in The Astrophysical Journal