Electrokinetic Current Driven by a Viscosity Gradient

Abstract

Gradients of voltage, pressure, temperature, and salinity can transport objects in micro- and nanofluidic systems by well known mechanisms. Here we report the discovery of a transport effect driven by viscosity gradients, which cause an ionic current to flow inside a glass nanofluidic channel. Measurements of the current are well described by a simple model wherein counterions in the electric double layers near the surfaces drift in the direction of decreasing viscosity with a drift speed equal to the gradient of the ions' local diffusivity. Drift in a viscosity gradient is a consequence of multiplicative (state-dependent) noise, which results from a particle's thermal fluctuations depending on its position. This surprisingly large effect, measured in a highly controlled nanofluidic environment, reveals fundamental behavior that is relevant to a broad range of systems.