A Review of Experimental Solubilities and a General Correlation between the Temperature-Dependent Solubility and Solute and Solvent Molar Masses for Binary n-Alkane Mixtures

Abstract

The solubility of a "heavy" alkane (solute) in a "light" alkane (solvent) is generally temperature dependent. Moreover, it is determined by the molar masses of the solute and solvent. In the current paper, published solubility data for binary normal-alkane mixtures is reviewed (solid-liquid equilibrium). A total of 43 unique solute-solvent data-sets, obtained from a total of 24 published experimental studies, are collected and presented in a systematic manner. Based on thermodynamic considerations and the experimental data, it is demonstrated that there is a log-linear relationship between the solubility and the temperature in the dilute range. Linear regression is employed to 1) obtain data-set-specific solubility-temperature best-fit parameters and 2) obtain a general correlation between the solubility and the solvent and solute molar masses and the temperature. Finally, it is demonstrated that the developed correlation carries predictive power even for multi-component mixtures by utilizing solvent and solute average molar masses.

arXiv commentAccepted for publication in Fluid Phase Equilibria (Elsevier) in Jan. 2022. 16 pages, 6 figures (Fig. 6 contains 43 subfigures). Published data for binary normal-alkane mixtures reviewed. 43 solute-solvent data-sets, from 24 references are revisited. Linear regression used to establish a general correlation between solubility, solvent/solute molar masses and temperature