Electric field distortions in structures of the twist bend nematic (NTB) phase of a bent-core liquid crystal
arXiv:1805.02936 · doi:10.1103/PhysRevE.98.022704
Abstract
Dielectric spectroscopy of a twist bend nematic phase of an achiral bent core liquid crystalline compound under DC bias is used to investigate its response to electric field. Two collective relaxation processes are revealed, these are assigned to distortions of helicoidal structure by the external bias field. Frequency of the mode depends primarily on the helicoidal angle and has anomalous, softening- like behaviour at the nematic to the twist bend nematic transition. A coupling of dielectric anisotropy with electric field gives rise to a new equilibrium periodic structure in the time scale involved. The modulus of the wave vector gradually vanishes on increasing the bias field (except for the initial behaviour, which is just the opposite). Transition from the twist bend to the splay bend structure is clearly observed by a sudden drop in the frequency of this mode, which decreases almost linearly with increasing field. Results agree with predictions from current models for the periodically distorted a twist bend nematic phase.
arXiv comment14 PAGES, 7 FIGURES, submitted to Physical Review Letters
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- Structure of the twist-bend nematic phase with respect to the orientational molecular order of the thioether-linked dimers
- Conformational degrees of freedom and stability of splay-bend ordering in the limit of a very strong planar anchoring
- Molecular biaxiality determines the helical structure -- Infrared measurements of the molecular order in the NTB phase of difluoro terphenyl dimers
- Nematic twist-bend phase of a bent liquid crystal dimer: field-induced deformations of the helical structure, macroscopic polarization and fast switching speeds
- Confinement Reveals Hidden Splay-Bend Order in Twist-Bend Nematics