On the Balance of Intercalation and Conversion Reactions in Battery Cathodes

Abstract

We present a thermodynamic analysis of the driving forces for intercalation and conversion reactions in battery cathodes across a range of possible working ion, transition metal, and anion chemistries. Using this body of results, we analyze the importance of polymorph selection as well as chemical composition on the ability of a host cathode to support intercalation reactions. We find that the accessibility of high energy charged polymorphs in oxides generally leads to larger intercalation voltages favoring intercalation reactions, whereas sulfides and selenides tend to favor conversion reactions. Furthermore, we observe that Cr-containing cathodes favor intercalation more strongly than those with other transition metals. Finally, we conclude that two-electron reduction of transition metals (as is possible with the intercalation of a $2+$ ion) will favor conversion reactions in the compositions we studied.

References in corpus (3)

• Role of structural H${}_2$O in intercalation electrodes: the case of Mg in nano-crystalline Xerogel-V${}_2$O${}_5$
• The intercalation phase diagram of Mg in V${}_2$O${}_5$ from first principles
• Influence of inversion on Mg mobility and electrochemistry in spinels

Cited by in corpus (7)

• Evaluation of Mg compounds as coating materials in Mg batteries
• Phase Stability and Sodium-Vacancy Orderings in a NaSICON Electrode
• Searching Ternary Oxides and Chalcogenides as Positive Electrodes for Calcium Batteries
• Exploration of amorphous V${}_2$O${}_5$ as cathode for magnesium batteries
• Exploration of oxyfluoride frameworks as Na-ion cathodes
• Fluoride Frameworks as Potential Calcium Battery Cathodes
• Ionic Transport in Potential Coating Materials for Mg Batteries