Maximum spin polarization in chromium dimer cations as demonstrated by x-ray magnetic circular dichroism spectroscopy

Abstract

X-ray magnetic circular dichroism spectroscopy has been used to characterize the electronic structure and magnetic moment of Cr${}_2^{+}$. Our results indicate that the removal of a single electron from the $4s{\sigma }_g$ bonding orbital of Cr${}_2$ drastically changes the preferred coupling of the $3d$ electronic spins. While the neutral molecule has a zero-spin ground state with a very short bond length, the molecular cation exhibits a ferromagnetically coupled ground state with the highest possible spin of $S=11/2$, and almost twice the bond length of the neutral molecule. This spin configuration can be interpreted as a result of indirect exchange coupling between the $3d$ electrons of the two atoms that is mediated by the single $4s$ electron through a strong intraatomic $3d$-$4s$ exchange interaction. Our finding allows an estimate of the relative energies of two states that are often discussed as ground-state candidates, the ferromagnetically coupled ${}^{12}\Sigma$ and the low-spin ${}^2\Sigma$ state.

This is the peer-reviewed, accepted version of the article