Gapped ground state in the zigzag pseudospin-1/2 quantum antiferromagnetic chain compound PrTiNbO6

Abstract

We report a single-crystal study on the magnetism of the rare-earth compound PrTiNbO${}_6$ that experimentally realizes the zigzag pseudospin-$\frac{1}{2}$ quantum antiferromagnetic chain model. Random crystal electric field caused by the site mixing between non-magnetic Ti${}^{4+}$ and Nb${}^{5+}$, results in the non-Kramers ground state quasi-doublet of Pr${}^{3+}$ with the effective pseudospin-$\frac{1}{2}$ Ising moment. Despite the antiferromagnetic intersite coupling of about 4 K, no magnetic freezing is detected down to 0.1 K, whilst the system approaches its ground state with almost zero residual spin entropy. At low temperatures, a sizable gap of about 1 K is observed in zero field. We ascribe this gap to off-diagonal anisotropy terms in the pseudospin Hamiltonian, and argue that rare-earth oxides open an interesting venue for studying magnetism of quantum spin chains.

11 pages, 10 figures, 1D correlated magnetism of non-Kramers Ising quasi-doublets in PrTiNbO6