Analytical expression for end-to-end- auto correlation function of a long chain polymer molecule in solution

Abstract

A diffusion-like theory for real time end-to-end distance of a long polymer chain in dilute solution is formulated. We give a detailed analytical expression for the end-to-end distance auto-correlation function of a long chain polymer in solution. The physical problem of dynamics of end-to-end distance can be modeled mathematically with the use of a Smoluchowski-like equation. Using this equation analytical expression for end-to-end distance auto-correlation function is derived. We find that this auto-correlation function varies with several parameters such as length of the polymer (N), bond length (b) and the relaxation time ${\tau }_R$.