Large deviations of reaction fluxes
arXiv:1802.02512 · doi:10.1007/s11040-019-9318-4
Abstract
We study a system of interacting particles that randomly react to form new particles. The reaction flux is the rescaled number of reactions that take place in a time interval. We prove a dynamic large-deviation principle for the reaction fluxes under general assumptions that include mass-action kinetics. This result immediately implies the dynamic large deviations for the empirical concentration.
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