Structural behavior of supercritical fluids under confinement

Abstract

The location of the Frenkel line (FL) of a Lennard-Jones fluid which demarcates two distinct physical states, liquidlike and gaslike within the supercritical regime, has been established through molecular dynamics (MD) simulations of the velocity auto-correlation (VACF) and Radial distribution Function (RDF). We, in this article, explore the changes in the structural features of supercritical LJ-fluid under partial confinement using atomistic walls. The study is carried out across the FL through a series of MD simulations considering a set of thermodynamics states in the supercritical regime of Argon well above the critical point. Confinement is partial, with atomistic walls located normal to z and extending to "infinity" along the x and y directions. In the "liquidlike" regime of the supercritical phase, particles are distributed in distinct layers along the z with layer spacing less than one atomic diameter and the lateral RDF showing amorphous-like structure for specific spacings (packing frustration). Increasing the rigidity of the atomistic walls is found to lead to stronger layering and increased structural order. For confinement with reflective walls, layers are found to form with one atomic diameter spacing and the lateral RDF showing close-packed structure for the smaller confinements. Translational order parameter and excess entropy assessment confirm the ordering taking place for atomistic wall and reflective wall confinements. In the "gaslike" regime of the supercritical phase, particle distribution along the spacing and the lateral RDF exhibit features not significantly different from that due to the normal gas regime. The heterogeneity across FL, found to be present both in bulk and confined systems, might cause the breakdown of the universal scaling between structure and dynamics of fluids necessitating the determination of a unique relationship between them.

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Cited by in corpus (7)

• Transition in the supercritical state of matter: experimental evidence
• Topological generalization of the rigid-nonrigid transition in soft-sphere and hard-sphere fluids
• Soft-wall induced structure and dynamics of partially confined supercritical fluids
• Anomaly of the dielectric function of water under confinement and its role in Van der Waals interactions
• Dynamic properties of quasi-confined colloidal hard-sphere liquids near the glass transition
• Minkowski functionals for phase behavior under confinement
• Effects of Structural Inhomogeneity on Equilibration Processes in Langevin Dynamics