Planar screening by charge polydisperse counterions

Abstract

We study how a neutralising cloud of counterions screens the electric field of a uniformly charged planar membrane plate, when the counterions are characterised by a distribution of charges (or valence), $n(q)$. We work out analytically the one-plate and two-plate cases, at the level of non-linear Poisson-Boltzmann theory. The (essentially asymptotic) predictions are successfully compared to numerical solutions of the full Poisson-Boltzmann theory, but also to Monte Carlo simulations. The counterions with smallest valence control the long-distance features of interactions, and may qualitatively change the results pertaining to the classic monodisperse case where all counterions have the same charge. Emphasis is put on continuous distributions $n(q)$, for which new power-laws can be evidenced, be it for the ionic density or the pressure, in the one- and two-plates situations respectively. We show that for discrete distributions, more relevant for experiments, these scaling laws persist in an intermediate but yet observable range. Furthermore, it appears that from a practical point of view, hallmarks of the continuous $n(q)$ behaviour is already featured by discrete mixtures with a relatively small number of constituents.

arXiv comment23 pages, 10 figures

References in corpus (12)

• Electrostatic correlations: from Plasma to Biology
• Electrostatic Interactions in Strongly-Coupled Soft Matter
• Effective charge saturation in colloidal suspensions
• Suppressed compressibility at large scale in jammed packings of size disperse spheres
• Onsager-Manning-Oosawa condensation phenomenon and the effect of salt
• On Exact Solutions to the Cylindrical Poisson-Boltzmann Equation with Applications to Polyelectrolytes
• Non-linear screening of spherical and cylindrical colloids: the case of 1:2 and 2:1 electrolytes
• Optimal packing of polydisperse hard-sphere fluids
• A density functional theory study of electric potential saturation: planar geometry
• The contact theorem for charged fluids: from planar to curved geometries
• Continuous phase transition in polydisperse hard-sphere mixture
• Quasi-universality in mixed counterions systems

Cited by in corpus (1)

• A correlation-hole approach to the electric double layer with counter-ions only