Kinetic Monte Carlo Model of Breakup of Nanowires into Chains of Nanoparticles

Abstract

A kinetic Monte Carlo approach is applied to studying shape instability of nanowires that results in their breaking up into chains of nanoparticles. Our approach can be used to explore dynamical features of the process that correspond to experimental findings, but that cannot be interpreted by continuum mechanisms reminiscent of the description of the Plateau-Rayleigh instability in liquid jets. For example, we observe long-lived dumbbell-type fragments and other typical non-liquid-jet characteristics of the process, as well as confirm the observed lattice-orientation dependence of the breakup process of single-crystal nanowires. We provide snapshots of the process dynamics, and elaborate on the nanowire-end effects, as well as on the morphology of the resulting nanoparticles.

References in corpus (5)

• Surface Fluctuations and the Stability of Metal Nanowires
• Models of Synthesis of Uniform Colloids and Nanocrystals
• Nonequilibrium Kinetic Modeling of Sintering of a Layer of Dispersed Nanocrystals
• Mechanisms of Interparticle Bridging in Sintering of Dispersed Nanoparticles
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Cited by in corpus (4)

• Effect of Transport Mechanism on the Coarsening of Bicontinuous Structures: A Comparison between Bulk and Surface Diffusion
• Diversity of anisotropy effects in the breakup of metallic FCC nanowires into ordered nanodroplet chains
• Restructuring and Breakup of Nanowires with the Diamond Cubic Crystal Structure into Nanoparticles
• Roughening transition as a driving factor in the formation of self