Cholesteric and screw-like nematic phases in systems of helical particles

Abstract

Recent numerical simulations of hard helical particle systems unveiled the existence of a novel chiral nematic phase, termed screw-like, characterised by the helical organization of the particle C${}_2$ symmetry axes round the nematic director with periodicity equal to the particle pitch. This phase forms at high density and can follow a less dense uniform nematic phase, with relative occurrence of the two phases depending on the helix morphology. Since these numerical simulations were conducted under three-dimensional periodic boundary conditions, two questions could remain open. Firstly, the real nature of the lower density nematic phase, expected to be cholesteric. Secondly, the influence that the latter, once allowed to form, may have on the existence and stability of the screw-like nematic phase. To address these questions, we have performed Monte Carlo and molecular dynamics numerical simulations of helical particle systems confined between two parallel repulsive walls. We have found that removal of the periodicity constraint along one direction allows a relatively-long-pitch cholesteric phase to form, in lieu of the uniform nematic phase, with helical axis perpendicular to the walls while the existence and stability of the screw-like nematic phase are not appreciably affected by this change of boundary conditions.

References in corpus (5)

• Cholesterics of colloidal helices: Predicting the macroscopic pitch from the particle shape and thermodynamic state
• Density Functional Theory for Chiral Nematic Liquid Crystals
• From rods to helices: evidence of a screw-like nematic phase
• Left or right cholesterics? A matter of helix handedness and curliness
• Spontaneous sense inversion in helical mesophases

Cited by in corpus (1)

• The Thermodynamic Origins of Chiral Twist in Monolayer Assemblies of Hard Rod-like Colloids