Sulphur-bearing molecules in AGB stars I: The occurrence of hydrogen sulfide

Abstract

Through a survey of (sub-)millimetre emission lines of various sulphur-bearing molecules, we aim to determine which molecules are the primary carriers of sulphur in different types of AGB stars. In this paper, the first in a series, we investigate the occurrence of H${}_2$S in AGB circumstellar envelopes and determine its abundance, where possible. We have surveyed 20 AGB stars with a range of mass-loss rates and of different chemical types using the APEX telescope to search for rotational transition lines of five key sulphur-bearing molecules: CS, SiS, SO, SO${}_2$ and H${}_2$S. Here we present our results for H${}_2$S, including detections, non-detections and detailed radiative transfer modelling of the detected lines. We compare results based on different descriptions of the molecular excitation of H${}_2$S and different abundance distributions, including those derived from chemical modelling results. We detected H${}_2$S towards five AGB stars, all of which have high mass-loss rates of $\dot{M}\ge 5\times 10^{-6}{M}_{\odot }$ yr${}^{-1}$ and are oxygen-rich. H${}_2$S was not detected towards the carbon or S-type stars that fall in a similar mass-loss range. For the stars in our sample with detections, we find peak o-H${}_2$S abundances relative to H${}_2$ between $4\times 10^{-7}$ and $2.5\times 10^{-5}$. Overall, we conclude that H${}_2$S can play a significant role in oxygen-rich AGB stars with higher mass-loss rates, but is unlikely to play a key role in stars of other chemical types or the lower mass-loss rate oxygen-rich stars. For two sources, V1300 Aql and GX Mon, H${}_2$S is most likely the dominant sulphur-bearing molecule in the circumstellar envelope.

14 pages, 7 figures, accepted in A&A

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• Tunneling Reaction Kinetics for the Hydrogen Abstraction Reaction H + H${}_2$S -> H${}_2$ + HS in the Interstellar Medium
• An ALMA view of CS and SiS around oxygen-rich AGB stars
• The abundance of S- and Si-bearing molecules in O-rich circumstellar envelopes of AGB stars
• SiO, 29SiO, and 30SiO emission from 67 oxygen-rich stars. A survey of 61 maser lines from 7 to 1 mm
• The surprisingly carbon-rich environment of the S-type star W Aql
• CO line observations of OH/IR stars in the inner Galactic Bulge: Characteristics of stars at the tip of the AGB