Over the shear paradigm
arXiv:1706.07750 · doi:10.3390/cryst8040181
Abstract
Deformation twinning and martensitic transformations are displacive transformations; they are defined by high speed collective displacements of the atoms, the existence of a parent/daughter orientation relationship, and plate or lath morphologies. The current crystallographic models of deformation twinning in metals are based on the 150 year-old concept of simple shear. For martensitic transformations, a generalized version of simple shear called invariant plane strain takes into account the volume change; it is associated with one or two simple shears in the phenomenological theory of martensitic crystallography built more than 60 years ago. As simple shears would involve unrealistic stresses, dislocation/disconnection-mediated versions of the usual crystallographic models of displacive transformations have been developed over the last decades. However, fundamental questions remain unsolved. How do the atoms move? How could dislocations be created and propagate in a coordinated way at the speed of sound? In order to solve these issues an approach that is not based on simple shear nor on dislocation/disconnection has been applied to different displacive transformations over the last years. It assumes that the atoms are hard-spheres, which permits for any specific orientation relationship to determine the atomics trajectories, the lattice distortion and shuffling (if required) as analytical functions of a unique angular parameter. The aim of the present paper is to give a brief historical review of the current models based on the shear concept and of their dislocation-mediated versions, and to introduce the new paradigm of angular distortion. Examples will be taken by using some recent publications. The possibilities offers by this approach in mechanics and thermodynamics are briefly discussed.
100 pages, 36 figures, 168 references
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