High resolution quantum cascade laser spectroscopy of the simplest Criegee intermediate, CH${}_2$OO, between 1273 cm${}^{-1}$ and 1290 cm${}^{-1}$

Abstract

The region 1273-1290 cm${}^{-1}$ of the $\nu$4 fundamental of the simplest Criegee intermediate, CH${}_2$OO, has been measured using a quantum cascade laser transient absorption spectrometer, which offers greater sensitivity and spectral resolution (< 0.004 cm${}^{-1}$) than previous works based on thermal light sources. Gas phase CH${}_2$OO was generated from the reaction of CH${}_2$I + O2 at 298 K and 4 Torr. Analysis of the absorption spectrum has provided precise values for the vibrational frequency and the rotational constants, with fitting errors of a few MHz. The determined ratios of the rotational constants, A'/A" = 0.9986, B'/B" = 0.9974 and C'/C" = 1.0010, and the relative intensities of the a- and b-type transitions, 90:10, are in good agreement with literature values from a theoretical calculation using the MULTIMODE approach, based on a high-level ab initio potential energy surface. The low-K (= Ka) lines can be fitted extremely well, but rotational perturbations by other vibrational modes disrupt the structure for K = 4 and K $\ge$ 6. Not only the spectral resolution but also the detection sensitivity of CH${}_2$OO IR transitions has been greatly improved in this work, allowing for unambiguous monitoring of CH${}_2$OO in kinetic studies at low concentrations.