Collisional excitation of NH3 by atomic and molecular hydrogen

Abstract

We report extensive theoretical calculations on the rotation-inversion excitation of interstellar ammonia (NH3) due to collisions with atomic and molecular hydrogen (both para- and ortho-H2). Close-coupling calculations are performed for total energies in the range 1-2000 cm-1 and rotational cross sections are obtained for all transitions among the lowest 17 and 34 rotation-inversion levels of ortho- and para-NH3, respectively. Rate coefficients are deduced for kinetic temperatures up to 200 K. Propensity rules for the three colliding partners are discussed and we also compare the new results to previous calculations for the spherically symmetrical He and para-H2 projectiles. Significant differences are found between the different sets of calculations. Finally, we test the impact of the new rate coefficients on the calibration of the ammonia thermometer. We find that the calibration curve is only weakly sensitive to the colliding partner and we confirm that the ammonia thermometer is robust.

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• Variations of the HCO${}^{+}$, HCN, HNC, N${}_2$H${}^{+}$ and NH${}_3$ deuterium fractionation in high-mass star-forming regions
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• Mixed Quantum/Classical Theory for Rotational Energy Exchange in Symmetric-Top-Rotor + Linear-Rotor Collisions and a Case Study of $\mathrm{N}{\mathrm{D}}_3+{\mathrm{D}}_2$ System
• An accurate set of H${}_3$O${}^{+}-$ H${}_2$ collisional rate coefficients for non-LTE modelling of warm interstellar clouds
• Imaging scattering resonances in low-energy inelastic ND${}_3$-H${}_2$ collisions
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