Absolute frequency determination of molecular transition in the Doppler regime at kHz level of accuracy
arXiv:1705.06639 · doi:10.1016/j.jqsrt.2017.07.010
Abstract
We present absolute frequency measurement of the unperturbed P7 P7 O B-band transition with relative standard uncertainty of . We reached the level of accuracy typical for Doppler-free techniques, with Doppler-limited spectroscopy. The Doppler-limited shapes of the P7 P7 spectral line were measured with a frequency-stabilized cavity ring-down spectrometer referenced to an Sr optical atomic clock by an optical frequency comb.