Time-dependent analysis of the mixed-field orientation of molecules without rotational symmetry

Abstract

We present a theoretical study of the mixed-field orientation of molecules without rotational symmetry. The time-dependent one-dimensional and three-dimensional orientation of a thermal ensemble of 6-chloropyridazine-3-carbonitrile molecules in combined linearly or elliptically polarized laser fields and tilted dc electric fields is computed. The results are in good agreement with recent experimental results of one-dimensional orientation for weak dc electric fields [J. Chem. Phys. 139, 234313 (2013)]. Moreover, they predict that using elliptically polarized laser fields or strong dc fields three-dimensional orientation is obtained. The field-dressed dynamics of excited rotational states is characterized by highly non-adiabatic effects. We analyze the sources of these non-adiabatic effects and investigate their impact on the mixed-field orientation for different field configurations in mixed-field-orientation experiments.

arXiv comment12 pages, 11 figures, 4 movies and a description of these movies (CPC_paper_SI.pdf) as supplementary material; corrected typos, additional information in the caption of table 1

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Cited by in corpus (7)

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• Switched Wave Packets with Spectrally Truncated Chirped Pulses
• Detecting handedness of spatially oriented molecules by Coulomb explosion imaging
• Laser-induced dynamics of molecules with strong nuclear quadrupole coupling
• Theoretical study of asymmetric superrotors: alignment and orientation
• Long-Lasting Orientation of Symmetric-top Molecules Excited by Two-Color Femtosecond Pulses
• Analyzing laser-induced alignment of weakly-bound molecular aggregates