Dynamical reduction of the dimensionality of exchange interactions and the "spin-liquid" phase of $\hat{I}º$-(BEDT-TTF)${}_{2}X$

Abstract

We show that the anisotropy of the effective spin model for the dimer Mott insulator phase of $\hat{I}º$-(BEDT-TTF)${}_{2}X$ salts is dramatically different from that of the underlying tight-binding model. Intra-dimer quantum interference results in a model of coupled spin chains, where frustrated interchain interactions suppress long-range magnetic order. Thus, we argue, the "spin liquid" phase observed in some of these materials is a remnant of the Tomonaga-Luttinger physics of a single chain. This is consistent with previous experiments and resolves some outstanding puzzles. An erratum [Phys. Rev. Lett. 120, 199901 (2018).] is added as an appendix.

Accepted by PRL, 6 pages, 5 figures