Structure, magnetic susceptibility and specific heat of the spin-orbital-liquid candidate FeSc2S4 : Influence of fe off-stoichiometry

Abstract

We report structural, susceptibility and specific heat studies of stoichiometric and off-stoichiometric poly- and single crystals of the A-site spinel compound FeSc2S4. In stoichiometric samples no long-range magnetic order is found down to 1.8 K. The magnetic susceptibility of these samples is field independent in the temperature range 10 - 400 K and does not show irreversible effects at low temperatures. In contrast, the magnetic susceptibility of samples with iron excess shows substantial field dependence at high temperatures and manifests a pronounced magnetic irreversibility at low temperatures with a difference between ZFC and FC susceptibilities and a maximum at 10 K reminiscent of a magnetic transition. Single crystal x-ray diffraction of the stoichiometric samples revealed a single phase spinel structure without site inversion. In single crystalline samples with Fe excess besides the main spinel phase a second ordered single-crystal phase was detected with the diffraction pattern of a vacancy-ordered superstructure of iron sulfide, close to the 5C polytype Fe9S10. Specific heat studies reveal a broad anomaly, which evolves below 20 K in both stoichiometric and off-stoichiometric crystals. We show that the low-temperature specific heat can be well described by considering the low-lying spin-orbital electronic levels of Fe2+ ions. Our results demonstrate significant influence of excess Fe ions on intrinsic magnetic behavior of FeSc2S4 and provide support for the spin-orbital liquid scenario proposed in earlier studies for the stoichiometric compound.

arXiv comment36 pages, 19 figures

References in corpus (8)

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• Singlet-triplet excitations and long range entanglement in the spin-orbital liquid candidate FeSc2S4
• Excitation spectrum and magnetic field effects in a quantum critical spin-orbital system:FeSc${}_2$S${}_4$
• Antiferromagnetic and Orbital Ordering on a Diamond Lattice Near Quantum Criticality
• Spin-orbiton and quantum criticality in FeSc2S4
• Growth and Characterization of Iron Scandium Sulfide (FeSc2S4)
• Magnetic field dependence of excitations near spin-orbital quantum criticality

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