Apparent Reversal of Molecular Orbitals Reveals Entanglement

Abstract

The frontier orbital sequence of individual dicyanovinyl-substituted oligothiophene molecules is studied by means of scanning tunneling microscopy. On NaCl/Cu(111) the molecules are neutral and the two lowest unoccupied molecular states are observed in the expected order of increasing energy. On NaCl/Cu(311), where the molecules are negatively charged, the sequence of two observed molecular orbitals is reversed, such that the one with one more nodal plane appears lower in energy. These experimental results, in open contradiction with a single-particle interpretation, are explained by a many-body theory predicting a strongly entangled doubly charged ground state.

10 pages, 5 figures

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• Destructive quantum interference in transport through molecules with electron-electron and electron-vibration interactions
• Spin-orbit interaction induces charge beatings in a lightwave-STM single molecule junction
• Many-Body Coherence in Quantum Transport
• Substrate stabilization of Jahn-Teller distortion in a single molecule
• The multiconfigurational ground state of a diradicaloid characterized at the atomic scale