Revealing the Link between Structural Relaxation and Dynamic Heterogeneity in Glass-Forming Liquids

Abstract

Despite the use of glasses for thousands of years, the nature of the glass transition is still mysterious. On approaching the glass transition, the growth of dynamic heterogeneity has long been thought to play a key role in explaining the abrupt slowdown of structural relaxation. However, it still remains elusive whether there is an underlying link between structural relaxation and dynamic heterogeneity. Here we unravel the link by introducing a characteristic time scale hiding behind an identical dynamic heterogeneity for various model glass-forming liquids. We find that the time scale corresponds to the kinetic fragility of liquids. Moreover, it leads to scaling collapse of both the structural relaxation time and dynamic heterogeneity for all liquids studied, together with a characteristic temperature associated with the same dynamic heterogeneity. Our findings imply that studying the glass transition from the viewpoint of dynamic heterogeneity is more informative than expected.

arXiv comment5 pages, 3 figures

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• Understanding Flow Behaviors of Supercooled Liquids by Embodying Solid-Liquid Duality at Particle Level
• Changing the universality class of the three-dimensional Edwards-Anderson spin-glass model by selective bond dilution
• Non Gaussian information of heterogeneity in Soft Matter
• Probing the Local Response of Glass-forming Liquids by Laser Excitations