Ensemble dependence of fluctuations and the canonical/micro-canonical equivalence of ensembles
arXiv:1701.07705 · doi:10.1007/s10955-017-1830-y
Abstract
We study the equivalence of microcanonical and canonical ensembles in continuous systems, in the sense of the convergence of the corresponding Gibbs measures. This is obtained by proving a local central limit theorem and a local large deviations principle. As an application we prove a formula due to Lebowitz-Percus-Verlet. It gives mean square fluctuations of an extensive observable, like the kinetic energy, in a classical micro canonical ensemble at fixed energy.
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