Analytic evaluation of some three- and four- electron atomic integrals involving s STO's and exponential correlation with unlinked $r_{ij}$'s

Abstract

The method of evaluation outlined in a previous work has been utilized here to evaluate certain other three- electron and four- electron atomic integrals involving s Slater-type orbitals and exponential correlation with unlinked $r_{ij}$'s. Limiting expressions for various such integrals have been derived, which has not been done earlier. Closed-form expressions for $<r_{12}{r}_{13}/r_{14}>$, $<r_{12}{r}_{34}/r_{23}>$, $<r_{12}{r}_{23}/r_{34}>$, $<r_{12}{r}_{13}/r_{34}>$ and $<r_{12}{r}_{34}/r_{13}>$ have been obtained.

35 pages