Phase-channel dynamics reveal the role of impurities and screening in a quasi-one-dimensional charge-density wave system

Abstract

We investigate the low-energy phase excitations of the quasi-one-dimensional charge density wave (CDW) in ${\mathrm{K}}_{0.3}\mathrm{Mo}{\mathrm{O}}_3$, by direct probing of infrared-active CDW-lattice modes (phase-phonons) with ultrafast terahertz spectroscopy. Both the nonequilibrium response and temperature dependence of the bands are reconciled by generalizing the time-dependent Ginzburg-Landau theory, beyond that previously applied to the amplitude-phonons, to include impurity effects, while the photoinduced blue-shifts are attributed to a reduction of the electron-phonon coupling induced by a long-lived free-carrier population.