Highly Efficient Fuel Cell Electrodes from Few-Layer Graphene Sheets and Electrochemically Deposited Palladium Nanoparticles

Abstract

An extremely efficient ethanol fuel cell electrode is produced by combining the large surface area of vertically oriented and highly conductive few-layer graphene sheets with electrochemically deposited palladium nanoparticles. The electrodes show an extraordinary high catalyst activity of up to 7977 mA/(mg Pd) at low catalyst loadings of 0.64 $\mu$g/cm${}^2$ and a very high current density of up to 106 mA/cm${}^2$ at high catalyst loadings of 83 $\mu$g/cm${}^2$. Moreover, the low onset potentials combined with a good poisoning resistance and long-term stability make these electrodes highly suitable for real applications. These features are achieved by using a newly developed electrochemical catalyst deposition process exploiting high voltages of up to 3.5 kV. This technique allows controlling the catalyst amount ranging from a homogeneous widespread distribution of small ($\le$ 10 nm) palladium nanoparticles to rather dense layers of particles, while every catalyst particle has electrical contact to the graphene electrode.

This document is the Accepted Manuscript version of a Published Work that appeared in final form in J. Phys. Chem. C, copyright © American Chemical Society after peer review and technical editing by the publisher