Phase separation on the sphere: Patchy particles and self-assembly

Abstract

Motivated by observations of heterogeneous domain structure on the surface of cells, we consider a minimal model to describe the dynamics of phase separation on the surface of a spherical particle. Finite-size effects on the curved particle surface lead to the formation of long-lived, metastable states for which the density is distributed in patches over the particle surface. We study the time evolution and stability of these states as a function of both the particle size and the thermodynamic parameters. Finally, by connecting our findings with studies of patchy particles, we consider the implications for self-assembly in many-particle systems.

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Cited by in corpus (3)

• Classical dynamical density functional theory: from fundamentals to applications
• Self-assembled structures of colloidal dimers and disks on a spherical surface
• Nucleation on a sphere: the roles of curvature, confinement and ensemble