paper

Superconductivity at 35 K by self doping in RbGdFeAsO

arXiv:1606.08161 · doi:10.1088/1361-648X/aa58d2

Abstract

We report synthesis, crystal structure and physical properties of a novel quinary compound RbGdFeAsO. The new iron oxyarsenide is isostructural to the fluo-arsenide KCaFeAsF, both of which contain separate double FeAs layers that are self hole-doped in the stoichiometric composition. Bulk superconductivity at = 35 K is demonstrated by the measurements of electrical resistivity, dc magnetic susceptibility and heat capacity. An exceptionally high value of the initial slope of the upper critical field (d/d = 16.5 T/K) is measured for the polycrystalline sample.

10 pages, 6 figures, 1 table, the crystal structure is amended