Enhancing Perovskite Electrocatalysis through Strain Tuning of the Oxygen Deficiency

Abstract

Oxygen vacancies in transition metal oxides facilitate catalysis critical for energy storage and generation. However, it has proven elusive to promote vacancies at the lower temperatures required for operation in devices such as metal-air batteries and portable fuel cells. Here, we use thin films of the perovskite-based strontium cobaltite (SrCoOx) to show that epitaxial strain is a powerful tool towards manipulating the oxygen content under conditions consistent with the oxygen evolution reaction, yielding increasingly oxygen deficient states in an environment where the cobaltite would normally be fully oxidized. The additional oxygen vacancies created through tensile strain enhance the cobaltite catalytic activity towards this important reaction by over an order of magnitude, equaling that of precious metal catalysts, including IrO2. Our findings demonstrate that strain in these oxides can dictate oxygen stoichiometry independent of ambient conditions, allowing unprecedented control over oxygen vacancies essential in catalysis near room temperature.

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• Near-Room Temperature Ferromagnetic Insulating State in Highly Distorted LaCoO2.5 with CoO5 Square Pyramids
• Oxygen vacancies in strained SrTiO${}_3$ thin films: formation enthalpy and manipulation
• Reversible Thermal Strain Control of Oxygen Vacancy Ordering in an Epitaxial La${}_{0.5}$Sr${}_{0.5}$CoO${}_{3-\delta }$ Film
• Nanonionics and interfaces for energy and information technologies
• Awakening catalytically active surface of BaRuO3 thin film for alkaline hydrogen evolution
• Unveiling the critical role of interfacial strain in adjusting electronic phase transitions in correlated vanadium dioxide