Elastic aging from coexistence and transformations of ferroelectric and antiferroelectric states in PZT

Abstract

Materials undergoing antiferroelectric/ferroelectric (AFE/FE) transitions are studied for possible applications that exploit the large volume, charge and entropy differences between the two states, such as electrocaloric cooling, energy storage, electromechanical actuators. Though certain compositions of PZT codoped with La and Sn may withstand millions of electrically induced AFE/FE cycles, in other cases few thermally induced cycles and room temperature aging may cause noticeable changes in the material properties. This is particularly evident in the elastic moduli, which at room temperature can become as much as four times softer. In order to get more insight into the mechanisms involved in such elastic aging and full recovering with mild annealing at 600-800 K, the effect of La doping on PZT with 4.6% Ti is studied with anelastic measurements. Complete suppression of the time dependent phenomena is found after the transformation of the intermediate FE phase into incommensurate AFE by 2% La doping. This is discussed in terms of disappearance of the stress and electric fields at the FE/AFE interfaces, in the light of the thermally activated anelastic relaxation processes that are observed at high temperature, and are due to mobile defects, presumably O vacancies.

References in corpus (5)

• Drift of charged defects in local fields as aging mechanism in ferroelectrics
• Space-charge mechanism of aging in ferroelectrics: an exactly solvable two-dimensional model
• Effects of coupling between octahedral tilting and polar modes on the phase diagram of PbZr1-xTixO3 (PZT)
• Piezoelectric softening in ferroelectrics: ferroelectric versus antiferroelectric PbZr${}_{1-x}$Ti${}_x$O${}_3$
• Effects of aging and annealing on the polar and antiferrodistortive components of the antiferroelectric transition in PZT

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