Length Scale of Correlated Dynamics in Ultra-thin Molecular Glasses

Abstract

Physical vapor deposition (PVD) is widely used in manufacturing ultra-thin layers of amorphous organic solids. Here, we demonstrate that these films exhibit a sharp transition from glassy solid to liquid-like behavior with thickness below 30 nm. This liquid-like behavior persists even at temperatures well below the glass transition temperature, T${}_{\mathrm{g}}$. The enhanced dynamics in these films can produce large scale morphological features during PVD and lead to a dewetting instability in films held at temperatures as low as T${}_{\mathrm{g}}$-35 K. We measure the effective viscosity of organic glass films by monitoring the dewetting kinetics. These measurements combined with cooling rate-dependent T${}_{\mathrm{g}}$ measurements show that the apparent activation barrier for rearrangement decreases sharply in films thinner than 30 nm. These observations suggest long-range facilitation of dynamics induced by the free surface, with dramatic effects on the properties of nano-scale amorphous materials.

5 pages, 4 figures

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