Generation of mechanical force by grafted polyelectrolytes in an electric field

Abstract

We study theoretically and by means of molecular dynamics (MD) simulations the generation of mechanical force by grafted polyelectrolytes in an external electric field, which favors its adsorption on the grafting plane. The force arises in deformable bodies linked to the free end of the chain. Varying the field, one controls the length of the non-adsorbed part of the chain and hence the deformation of the target body, i.e., the arising force too. We consider target bodies with a linear force-deformation relation and with a Hertzian one. While the first relation models a coiled Gaussian chain, the second one describes the force response of a squeezed colloidal particle. The theoretical dependencies of generated force and compression of the target body on applied field agree very well with the results of MD simulations. The analyzed phenomenon may play an important role in a future nano-machinery, e.g. it may be used to design nano-vices to fix nano-sized objects.

arXiv commentPublished in Phys. Rev. E 93, 032505 (2016)

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Cited by in corpus (4)

• Metal-Organic Framework Breathing in Electric Field: A Theoretical Study
• Macroscopic forces in inhomogeneous polyelectrolyte solutions
• Electrochemistry meets polymer physics: polymerized ionic liquids on an electrified electrode
• Generation of mechanical force by grafted polyelectrolytes in an electric field. Application to polyelectrolyte-based nano-devices