Nuclear spin correlations and collective excitations in supercritical H${}_2$

Abstract

Nuclear spins are known to experience spontaneous long-range correlations only below 2.5 mili-Kelvin in superfluid ${}^3$He. Here we present the first evidence of nuclear spin coupling in molecular hydrogen (H${}_2$) at 74-92 Kelvin using neutron scattering, showing a fundamental change in nature from the incoherent scattering universally expected from hydrogen, which reflects single particle properties of uncorrelated nuclear spins, to coherent, with a peak materializing on the elastic line, indicating H${}_2$-H${}_2$ nuclear spin correlations. In this novel phase, the dynamic response of the system also changes nature, and collective excitations with an effective mass of nine H${}_2$ are observed with inelastic scattering at momentum transfers up to 37 Å${}^{-1}$, corresponding to length scales smaller than the H-H bond, where previous experiments have always found single atom excitations. This novel behavior has only been observed from H${}_2$ within the subnanometer sized graphitic pores of a carbon material, marking the first demonstration that a confined materials environment can be used to control nuclear spin correlations.

Submitted 12-21-2015