Tracking the photodissociation probability of D${}_2^{+}$ induced by linearly chirped laser pulses

Abstract

In the presence of linearly varying frequency chirped laser pulses the photodissociation dynamics of D${}_2^{+}$ is studied theoretically after ionization of D${}_2$ . As a completion of our recent work (J. Chem. Phys. 143, 014305 (2015)) a comprehensive dependence on the pulse duration and delay time is presented in terms of total dissociation probabilities. Our numerical analysis carried out in the recently introduced light-induced conical intersection (LICI) framework clearly shows the effects of the changing position of the LICI which is induced by the frequency modulation of the chirped laser pulses. This impact is presented for positively, negatively and zero chirped short pulses.

21 pages, 5 figures, accepted in J. Chem. Phys

References in corpus (3)

• Observation of Quantum Interferences via Light Induced Conical Intersections in Diatomic Molecules
• Quantum Control of Photodissociation via Manipulation of Bond Softening
• Compression and collisions of chirped pulses in a dense two-level medium

Cited by in corpus (2)

• Towards controlling the dissociation probability by light-induced conical intersections
• CEP-Controlled Molecular Dissociation by Ultrashort Chirped Laser Pulses