Electronic Pair-Binding and Hund's Rule Violations in Doped
arXiv:1510.04704 · doi:10.1103/PhysRevB.93.165406
Abstract
We calculate the electronic properties of the - model on a molecule using the density-matrix renormalization group and show that Hund's first rule is violated and that for an average of three added electron per molecule, an effective attraction (pair-binding) arises for intermediate values of . Specifically, it is energetically favorable to put four electrons on one and two on a second rather than putting three on each. Our results show that a dominantly electronic mechanism of superconductivity is possible in doped .
4 pages, 2 figures, plus appendix