From Hunds insulator to Fermi liquid: Optical spectroscopy study of K doping in BaMn${}_2$As${}_2$

Abstract

We present optical transmission measurements that reveal a charge gap of 0.86 eV in the local moment antiferromagnetic insulator BaMn${}_2$As${}_2$, an order of magnitude larger than previously reported. Density functional theory plus dynamical mean field theory (DFT+DMFT) calculations correctly reproduce this charge gap only when a strong Hund's coupling is considered. Thus, BaMn${}_2$As${}_2$ is a member of a wider class of Mn pnictide compounds that are Mott-Hund's insulators. We also present optical reflectance for metallic 2% K doped BaMn${}_2$As${}_2$ that we use to extract the optical conductivity at different temperatures. The optical conductivity ${\sigma }_1$($\omega$) exhibits a metallic response that is well described by a simple Drude term. Both $\sigma$($\omega$$\to$0, T) and $\rho$(T) exhibit Fermi liquid temperature dependencies. From these measurements, we argue that a more strongly correlated Hund's metal version of the parent compounds of the iron pnictide superconductors has not yet been realized by doping this class of Hund's insulators.