Common effect of chemical and external pressures on the magnetic properties of CoPO ( = La, Pr, Nd, Sm). II
arXiv:1506.06211 · doi:10.1103/PhysRevB.92.144414
Abstract
The direct correspondence between Co band ferromagnetism and structural parameters is investigated in the pnictide oxides CoPO for different rare-earth ions ( = La, Pr, Nd, Sm) by means of muon-spin spectroscopy and {\it ab-initio} calculations, complementing our results published previously [G. Prando {\it et al.}, {\it Phys. Rev. B} {\bf 87}, 064401 (2013)]. Both the transition temperature to the ferromagnetic phase and the volume of the crystallographic unit cell are found to be conveniently tuned by the ionic radius and/or external pressure. A linear correlation between and is reported and {\it ab-initio} calculations unambiguously demonstrate a full equivalence of chemical and external pressures. As such, ions are shown to be influencing the ferromagnetic phase only via the induced structural shrinkage without involving any active role from the electronic degrees of freedom, which are only giving a sizeable magnetic contribution at much lower temperatures.
8 pages, 5 figures
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