Direct Measure of Giant Magnetocaloric Entropy Contributions in Ni-Mn-In

Abstract

Off-stoichiometric alloys based on Ni 2 MnIn have drawn attention due to the coupled first order magnetic and structural transformations, and the large magnetocaloric entropy associated with the transformations. Here we describe calorimetric and magnetic studies of four compositions. The results provide a direct measure of entropy changes contributions including at the first-order phase transitions, and thereby a determination of the maximum field-induced entropy change corresponding to the giant magnetocaloric effect. We find a large excess entropy change, attributed to magneto-elastic coupling, but only in compositions with no ferromagnetic order in the high-temperature austenite phase. Furthermore, a molecular field model corresponding to antiferromagnetism of the low-temperature phases is in good agreement, and nearly independent of composition, despite significant differences in overall magnetic response of these materials.

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Cited by in corpus (5)

• Lattice vibrations boost demagnetization entropy in shape memory alloy
• Relative Cooling Power Enhancement by Tuning Magneto-structural Stability in Ni-Mn-In Heusler Alloys
• Thermo-magnetic characterization of phase transitions in a Ni-Mn-In metamagnetic shape memory alloy
• Influence of the martensitic transformation kinetics on the magnetocaloric effect in Ni-Mn-In
• Effect of site occupancy disorder on Martensitic properties of Mn${}_2$NiIn type alloys: x-ray absorption fine structure study