Nano-Ductility in Silicate Glasses is Driven by Topological Heterogeneity

Abstract

The existence of nanoscale ductility during the fracture of silicate glasses remains controversial. Here, based on molecular dynamics simulations coupled with topological constraint theory, we show that nano-ductility arises from the spatial heterogeneity of the atomic network's rigidity. Specifically, we report that localized floppy modes of deformation in under-constrained regions of the glass enable plastic deformations of the network, resulting in permanent change in bond configurations. Ultimately, these heterogeneous plastic events percolate, thereby resulting in a non-brittle mode of fracture. This suggests that nano-ductility is intrinsic to multi-component silicate glasses having nanoscale heterogeneities.

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Cited by in corpus (6)

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• Revealing the Atomic Structure of Silicate Glasses by Force-Enhanced Atomic Refinement
• Roughness and scaling properties of oxide glass surfaces at the nanoscale
• Statistical Mechanics of Topological Fluctuations in Glass-Forming Liquids
• The origin of phase separation in binary aluminosilicate glasses
• Strength of 2D Glasses Explored by Machine-Learning Force Fields