Discovery of SiCSi in IRC+10216: A missing link between gas and dust carriers of SiC bonds
arXiv:1505.01633 · doi:10.1088/2041-8205/806/1/L3
Abstract
We report the discovery in space of a disilicon species, SiCSi, from observations between 80 and 350 GHz with the IRAM 30m radio telescope. Owing to the close coordination between laboratory experiments and astrophysics, 112 lines have now been detected in the carbon-rich star CWLeo. The derived frequencies yield improved rotational and centrifugal distortion constants up to sixth order. From the line profiles and interferometric maps with the Submillimeter Array, the bulk of the SiCSi emis- sion arises from a region of 6 arcseconds in radius. The derived abundance is comparable to that of SiC2. As expected from chemical equilibrium calculations, SiCSi and SiC2 are the most abundant species harboring a SiC bond in the dust formation zone and certainly both play a key role in the formation of SiC dust grains.
arXiv commentTo be published in the Astrophysical Journal Letters; Accepted May 6 2015
References in corpus (17)
- Herschel Detects a Massive Dust Reservoir in Supernova 1987A
- Astronomical identification of CN-, the smallest observed molecular anion
- Detection of C5N- and vibrationally excited C6H in IRC +10216
- A stubbornly large mass of cold dust in the ejecta of Supernova 1987A
- Molecular abundances in the inner layers of IRC +10216
- New molecules in IRC+10216: confirmation of CS and tentative identification of MgCCH, NCCP, and SiHCN
- Detection of circumstellar CH2CHCN, CH2CN, CH3CCH and H2CS
- A high resolution line survey of IRC+10216 with Herschel. First results: Detection of warm silicon dicarbide SiC2
- Molecular shells in IRC+10216: tracing the mass loss history
- An Interferometric Spectral-line Survey of IRC+10216 in the 345 GHz Band
- Unveiling the dust nucleation zone of IRC+10216 with ALMA
- The size, luminosity and motion of the extreme carbon star IRC+10216 (CW Leonis)
- Discovery of Time Variation of the Intensity of Molecular Lines in IRC+10216 in The Submillimeter and Far Infrared Domains
- Formation of SiC Grains in Pulsation-Enhanced Dust-Driven Wind Around Carbon Rich Asymptotic Giant Branch Stars
- Si-bearing molecules towards IRC+10216: ALMA unveils the molecular envelope of CWLeo
- High-J v=0 SiS Maser Emission in IRC+10216: A New Case of Infrared Overlaps
- Spectroscopic parameters for silacyclopropynylidene, SiC, from extensive astronomical observations toward CW Leo (IRC +10216) with the Herschel satellite
Cited by in corpus (24)
- 2018 Census of Interstellar, Circumstellar, Extragalactic, Protoplanetary Disk, and Exoplanetary Molecules
- Chemical equilibrium in AGB atmospheres: Successes, failures, and prospects for small molecules, clusters, and condensates
- The millimeter IRAM-30m line survey toward IK Tau
- The Abundance of SiC2 in Carbon Star Envelopes: Evidence that SiC2 is a gas-phase precursor of SiC dust
- Nucleation of small silicon carbide dust clusters in AGB stars
- Discovery of the first Ca-bearing molecule in space: CaNC
- Study of CS, SiO, and SiS abundances in carbon star envelopes: Assessing their role as gas-phase precursors of dust
- Ab initio effective rotational and rovibrational Hamiltonians for non-rigid systems via curvilinear second order vibrational Møller-Plesset perturbation theory
- The abundance of C2H4 in the circumstellar envelope of IRC+10216
- Excited state quantum phase transitions in the bending spectra of molecules
- The abundance of 28Si32S, 29Si32S, 28Si34S, and 30Si32S in the inner layers of the envelope of IRC+10216
- Carbon chemistry in IRC+10216: Infrared detection of diacetylene
- A spectral line survey of IRC +10216 between 13.3 and 18.5 GHz
- Atmospheric molecular blobs shape up circumstellar envelopes of AGB stars
- Silicon and hydrogen chemistry under laboratory conditions mimicking the atmosphere of evolved stars
- Chemistry in AGB stars: successes and challenges
- Impact of metals on (star)dust chemistry: a laboratory astrophysics approach
- The Role of Ultraviolet Photons in Circumstellar Astrochemistry
- Multi-frequency high spectral resolution observations of HCN toward the circumstellar envelope of Y CVn
- A spectral survey of CH3CCH in the Hot Molecular Core G331.512-0.103
- Warm CO in evolved stars from the THROES catalogue. II. Herschel/PACS spectroscopy of C-rich envelopes
- The Abundance of SiC in Carbon Star Envelopes
- Laboratory Rotational Spectra of Silyl Isocyanide
- The Significant Role of Hydrogen in the Formation of Silicon Carbide in Evolved Stars