Transitions between the $4f$-core-excited states in Ir${}^{16+}$, Ir${}^{17+}$, and Ir${}^{18+}$ ions for clock applications

Abstract

Iridium ions near $4f$-$5s$ level crossings are the leading candidates for a new type of atomic clocks with a high projected accuracy and a very high sensitivity to the temporal variation of the fine structure constant $\alpha$. To identify spectra of these ions in experiment accurate calculations of the spectra and electromagnetic transition probabilities should be performed. Properties of the $4f$-core-excited states in Ir${}^{16+}$, Ir${}^{17+}$, and Ir${}^{18+}$ ions are evaluated using relativistic many-body perturbation theory and Hartree-Fock-Relativistic method (COWAN code). We evaluate excitation energies, wavelengths, oscillator strengths, and transition rates. Our large-scale calculations includes the following set of configurations: $4f^{14-k}5s^{m}5p^n$ with $(k+m+n)$ equal to 3, 2, and 1 for the Ir${}^{16+}$, Ir${}^{17+}$, and Ir${}^{18+}$ ions, respectively. The $5s-5p$ transitions are illustrated by the synthetic spectra in the 180 - 200 Årange. Large contributions of magnetic-dipole transitions to lifetimes of low-lying states in the region below 2.5 Ry are demonstrated.

10 pages

References in corpus (2)

• Hole transitions in multiply-charged ions for precision laser spectroscopy and searching for alpha-variation
• Highly charged ions with E1, M1, and E2 transitions within laser range

Cited by in corpus (3)

• Highly charged ions: optical clocks and applications in fundamental physics
• Accurate prediction of clock transitions in a highly charged ion with complex electronic structure
• Scalable codes for precision calculations of properties of complex atomic systems